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University College Dublin, Ireland
Title: Recent advances in asymmetric (green) catalysis
Biography

Pat Guiry Mria has completed his BSc and PhD from University College Dublin in 1986 and 1990, respectively. He pursued Post-doctoral Research with John M Brown, FRS at Oxford University 1990-1993 and was appointed as a College Lecturer in UCD in 1993. He has been full-time Professor at UCD since 2006 and is the Director of the Centre for Synthesis and Chemical Biology (2001-present) and was elected as a Member of the Royal Irish Academy in 2013. He has more than 130 publications that have been cited over 5650 times and has supervised 47 PhD students.

Abstract

This presentation will describe the design and synthesis of novel ferrocene-containing diols 1 as a novel scaffold for asymmetric catalysis and the novel axially chiral P,N ligand, UCD-PHIM and its applications in A3 coupling. The development of the Pd-catalysed decarboxylative asymmetric protonation for the preparation of ?-arylketones will be described, including recent advances in understanding the mechanisms involved in enantiodivergence and protonation with a chiral proton source.

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